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check the triple points of HF and H2; HF will liquify easily, H2 will not and therefore the pressure can increase. On Mon, 2005-07-11 at 07:23 -0400, Jim Kaufman wrote: > In a message dated 7/11/2005 12:02:39 AM Eastern Daylight Time, > LISTSERV**At_Symbol_Here**LIST.UVM.EDU writes: > > > 6HF + 2Fe yields 2FeF3 + 3H2 > > 2HF + Fe = FeF2 + H2 > > It does not matter whether it forms FeF3 or FeF2. In either case there will > be fewer gas molecules in the cylinder and the pressure will go down and not > up. > > Therefore, I agree with Jay (although it pains me to no extent), that > the tank ruptured because of the wall thinning. > > James A. Kaufman, Ph.D. > President/CEO > jimkaufman**At_Symbol_Here**labsafety.org > > The Laboratory Safety Institute > A Nonprofit International Organization for > Safety in Science and Science Education > > 192 Worcester Road, Natick, MA 01760-2252 > 508-647-1900 Fax: 508-647-0062 > Cell: 508-574-6264 Res: 781-237-1335 > info**At_Symbol_Here**labsafety.org www.labsafety.org
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